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Appl. Phys. Lett. 95, 052106 (2009); http://dx.doi.org/10.1063/1.3194153 (3 pages)

Chemical and electronic surface structure of 20%-efficient Cu(In,Ga)Se2 thin film solar cell absorbers

M. Bär1,2, I. Repins3, M. A. Contreras3, L. Weinhardt4, R. Noufi3, and C. Heske1

1Department of Chemistry, University of Nevada, Las Vegas, 4505 Maryland Parkway, P.O. Box 454003, Las Vegas, Nevada 89154-4003, USA
2Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie, Lise-Meitner-Campus, Glienicker Str. 100, 14109 Berlin, Germany
3National Renewable Energy Laboratory, Golden, 1617 Cole Blvd., Golden, Colorado 80401, USA
4Experimentelle Physik II, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

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(Received 29 May 2009; accepted 11 July 2009; published online 6 August 2009)

The chemical and electronic surface structure of 20%-efficient Cu(In,Ga)Se2 thin film solar cell absorbers was investigated as a function of deposition process termination (i.e., ending the growth process in absence of either Ga or In). In addition to the expected In (Ga) enrichment, direct and inverse photoemission reveal a decreased Cu surface content and a larger surface band gap for the “In-terminated” absorber.

© 2009 American Institute of Physics

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0003-6951 (print)  
1077-3118 (online)

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    References

    M. Morkel, L. Weinhardt, B. Lohmüller, C. Heske, E. Umbach, W. Riedl, S. Zweigart, and F. Karg, Appl. Phys. Lett. 79, 4482 (2001)APPLAB000079000027004482000001.

    M. Bär, S. Nishiwaki, L. Weinhardt, S. Pookpanratana, O. Fuchs, M. Blum, W. Yang, J. D. Denlinger, W. N. Shafarman, and C. Heske, Appl. Phys. Lett. 93, 244103 (2008)APPLAB000093000024244103000001.

    L. Weinhardt, C. Heske, E. Umbach, T. P. Niesen, S. Visbeck, and F. Karg, Appl. Phys. Lett. 84, 3175 (2004)APPLAB000084000016003175000001.

    M. Bär, W. Bohne, J. Röhrich, E. Strub, S. Lindner, M. C. Lux-Steiner, Ch. -H. Fischer, T. P. Niesen, and F. Karg, J. Appl. Phys. 96, 3857 (2004)JAPIAU000096000007003857000001.


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