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30 Apr 2012

Volume 100, Issue 18, Articles (18xxxx)

Issue Cover Spotlight Figure

Appl. Phys. Lett. 100, 181901 (2012); http://dx.doi.org/10.1063/1.4705414 (4 pages)

Etienne Brasselet, Arnaud Royon, and Lionel Canioni
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Highly efficient crystalline silicon/Zonyl fluorosurfactant-treated organic heterojunction solar cells

Qiming Liu, Masahiro Ono, Zeguo Tang, Ryo Ishikawa, Keiji Ueno, and Hajime Shirai

Appl. Phys. Lett. 100, 183901 (2012); http://dx.doi.org/10.1063/1.4709615 (4 pages) | Cited 6 times

Online Publication Date: 1 May 2012

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We demonstrate a highly efficient hybrid crystalline silicon (c-Si) based photovoltaic devices with hole-transporting transparent conductive poly-(3,4-ethlenedioxythiophene):poly(styrenesufonic acid) (PEDOT:PSS) films, incorporating a Zonyl fluorosurfactant as an additive, compared to non additive devices. The usage of a 0.1% Zonly treated PEDOT:PSS improved the adhesion of precursor solution on hydrophobic c-Si wafer without any oxidation process. The average power conversion efficiency η value was 10.8%-11.3%, which was superior to those of non-treated devices. Consequently, c-Si/Zonyl-treated PEDOT:PSS heterojunction devices exhibited the highest η of 11.34%. The Zonyl-treated soluble PEDOT:PSS composite is promising as a hole-transporting transparent conducting layer for c-Si/organic photovoltaic applications.
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88.40.hj Efficiency and performance of solar cells
88.40.jj Silicon solar cells

Calcium doped graphane as a hydrogen storage material

T. Hussain, B. Pathak, M. Ramzan, T. A. Maark, and R. Ahuja

Appl. Phys. Lett. 100, 183902 (2012); http://dx.doi.org/10.1063/1.4710526 (5 pages) | Cited 4 times

Online Publication Date: 1 May 2012

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On the basis of first principle density functional theory, we have studied the stability, electronic structure, and hydrogen storage capacity of a monolayer calcium doped graphane (CHCa). The stability of CHCa was further investigated using the ab initio molecular dynamics study. The binding energy of Ca on graphane sheet was found to be higher than its bulk cohesive energy, which indicates the stability of CHCa. It was observed that with a doping concentration of 11.11% of Ca on graphane sheet, a reasonably good H2 storage capacity of 6 wt. % could be attained. The adsorption energies of H2 were found to be 0.1 eV, within the range of practical H2 storage applications.
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61.72.U- Doping and impurity implantation
88.30.R- Hydrogen storage
68.43.Mn Adsorption kinetics
71.15.Nc Total energy and cohesive energy calculations
71.15.Pd Molecular dynamics calculations (Car-Parrinello) and other numerical simulations
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