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Appl. Phys. Lett. 53, 2644 (1988); doi:10.1063/1.100541 (3 pages)
Indium oxide diffusion barriers for Al/Si metallizations
(Received 25 August 1988; accepted 16 October 1988)
Indium oxide (In2O3) films were prepared by reactive rf sputtering of an In target in O2/Ar plasma. We have investigated the application of these films as diffusion barriers in 〈Si〉/In2O3/Al and 〈Si〉/TiSi2.3/In2O3/Al metallizations. Scanning transmission electron microscopy together with energy dispersive analysis of x ray of cross‐sectional Si/In2O3/Al specimens, and electrical measurements on shallow n+‐p junction diodes were used to evaluate the diffusion barrier capability of In2O3 films. We find that 100‐nm‐thick In2O3 layers prevent the intermixing between Al and Si in 〈Si〉/In2O3/Al contacts up to 650 °C for 30 min, which makes this material one of the best thin‐film diffusion barriers on record between Al and Si. (The Si‐Al eutectic temperature is 577 °C, Al melts at 660 °C.) When a contacting layer of titanium silicide is incorporated to form a 〈Si〉/TiSi2.3/In2O3/Al metallization structure, the thermal stability of the contact drops to 600 °C for 30 min heat treatment.
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M.-A. Nicolet, Thin Solid Films 54, 415 (1978APPLAB000050000026001879000001).
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