Appl. Phys. Lett. 78, 841 (2001); http://dx.doi.org/10.1063/1.1345834 (3 pages)
2.5% efficient organic plastic solar cells
(Received 10 August 2000; accepted 4 December 2000)
We show that the power conversion efficiency of organic photovoltaic devices based on a conjugated polymer/methanofullerene blend is dramatically affected by molecular morphology. By structuring the blend to be a more intimate mixture that contains less phase segregation of methanofullerenes, and simultaneously increasing the degree of interactions between conjugated polymer chains, we have fabricated a device with a power conversion efficiency of 2.5% under AM1.5 illumination. This is a nearly threefold enhancement over previously reported values for such a device, and it approaches what is needed for the practical use of these devices for harvesting energy from sunlight. © 2001 American Institute of Physics.
© 2001 American Institute of Physics
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- N. S. Sariciftci, L. Smilowitz, A. J. Heeger, and F. Wudl, Science 258, 1474 (1992)APPLAB000048000002000183000001.
- N. S. Sariciftci, D. Baun, C. Zhang, V. I. Srdanov, A. J. Heeger, G. Stucky, and F. Wudl, Appl. Phys. Lett. 62, 585 (1993)APPLAB000062000006000585000001.
- J. J. M. Halls, K. Pickler, R. H. Friend, S. C. Morati, and A. B. Holmes, Appl. Phys. Lett. 68, 3120 (1996)APPLAB000068000022003120000001. [ISI]
- G. Yu, J. Gao, J. C. Hummelen, F. Wudl, and A. J. Heeger, Science 270, 1789 (1995). [Inspec] [ISI]
- M. Granström, K. Petritsch, A. C. Arias, A. Lux, M. R. Andersson, and R. H. Friend, Nature (London) 395, 257 (1998).
- C. W. Tang, Appl. Phys. Lett. 48, 183 (1986)APPLAB000048000002000183000001.
- P. Peumans, V. Bulovic, and S. R. Forrest, Appl. Phys. Lett. 76, 2650 (2000)APPLAB000076000019002650000001.
- J. H. Schön, Ch. Kloc, E. Bucher, and B. Batlogg, Nature (London) 403, 408 (2000). [Inspec] [ISI] [MEDLINE]
- C. J. Brabec, F. Padinger, N. S. Sariciftci, and J. C. Hummelen, J. Appl. Phys. 85, 6866 (1999)JAPIAU000085000009006866000001. [ISI]
- G. E. Jabbour, B. Kippelen, N. R. Armstrong, and N. Peyghambarian, Appl. Phys. Lett. 73, 1185 (1998)APPLAB000073000009001185000001.
- L. S. Hung, C. W. Tang, and M. G. Mason, Appl. Phys. Lett. 70, 152 (1997)APPLAB000070000002000152000001.
- P. M. Sommeling, H. C. Rieffe, J. A. M. van Roosmalen, A. Schönecker, J. M. Kroon, J. A. Wienke, and A. Hinsch, Sol. Energy Mater. Sol. Cells 62, 399 (2000). [Inspec] [ISI]
- S. V. Rakhmanova and E. M. Conwell, Synth. Met. 116, 389 (2001).
- J. Cornil, J.-P. Calbert, D. Beljonne, D. A. dos Santos, and J.-L. Bredas, Mater. Res. Soc. Symp. Proc. 598 (1999).
- T. Q. Nguyen, I. B. Martini, J. Liu, and B. J. Schwartz, J. Phys. Chem. B 104, 237 (2000). [ISI]
- T.-Q. Nguyen, V. Doan, and B. J. Schwartz, J. Chem. Phys. 110, 4068 (1999)JCPSA6000110000008004068000001. [ISI]















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