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Appl. Phys. Lett. 79, 1977 (2001); http://dx.doi.org/10.1063/1.1405003 (3 pages)

Carrier localization and the origin of luminescence in cubic InGaN alloys

P. R. C. Kent and Alex Zunger

National Renewable Energy Laboratory, Golden, Colorado 80401

(Received 15 May 2001; accepted 31 July 2001)

The electronic structure and optical properties of cubic (nonpiezoelectric) InGaN are investigated using large scale atomistic empirical pseudopotential calculations. We find that (i) strong hole localization exists even in the homogeneous random alloy, with a preferential localization along the [1,1,0] In–N–In–N–In chains, (ii) even modest sized (<50 Å) indium rich quantum dots provide substantial quantum confinement and readily reduce emission energies relative to the random alloy by 200–300 meV, depending on size and composition, consistent with current photoluminescence, microscopy, and Raman data. The dual effects of alloy hole localization and localization of electrons and hole at intrinsic quantum dots are responsible for the emission characteristics of current grown cubic InGaN alloys. © 2001 American Institute of Physics.

© 2001 American Institute of Physics

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0003-6951 (print)  
1077-3118 (online)

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