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Appl. Phys. Lett. 85, 2089 (2004); doi:10.1063/1.1792380 (3 pages)
Photoconductivity from PbS-nanocrystal∕semiconducting polymer composites for solution-processible, quantum-size tunable infrared photodetectors
(Received 21 April 2004; accepted 13 July 2004)
We report photoconductivity at infrared wavelengths, 975–1300 nm, from a polymer∕nanocrystal quantum dot composite. Biased films of the conjugated polymer poly[2-methoxy-5-(2′-ethylhexyloxy-p-phenylenevinylene)] (MEH-PPV) sensitized with PbS nanocrystals (∼5 nm diameter) demonstrate photocurrent at wavelengths beyond the response of the polymer and corresponding to the absorption of the nanocrystals. The photocurrent is attributed to absorption in the nanocrystals with subsequent hole transfer to the polymer and had an internal quantum efficiency of ∼5×10−6 to ∼10−5 charges∕photon at 5 V bias.
© 2004 American Institute of Physics
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