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25 Jun 2007

Volume 90, Issue 26, Articles (26xxxx)

Issue Cover Spotlight Figure

Appl. Phys. Lett. 90, 262501 (2007); http://dx.doi.org/10.1063/1.2752015 (3 pages)

Ian Appelbaum and Douwe J. Monsma
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Atomic structure of In2O3ZnO systems

Yanfa Yan, Juarez L. F. Da Silva, Su-Huai Wei, and Mowafak Al-Jassim

Appl. Phys. Lett. 90, 261904 (2007); http://dx.doi.org/10.1063/1.2751596 (3 pages) | Cited 15 times

Online Publication Date: 25 June 2007

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The authors present first-principles density-functional theory studies on the atomic structure of the In2O3ZnO system. They find that the In2O3ZnO system has a polytypoid structure, which consists of wurtzite (Zn/In)O slabs separated by single In–O octahedral layers that are inversion boundaries. Another type of boundary with polarity inversion formed by fivefold coordinated In and Zn atoms exists inside the (Zn/In)O slabs. The authors find that these polarity-inversion boundaries inside the (Zn/In)O slabs prefer a low-energy modulated structure.
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61.66.Fn Inorganic compounds

Effect of microstructure on hydrogen permeation through thermally stable, sputtered palladium-silver alloy membranes

L. S. McLeod, F. L. Degertekin, and A. G. Fedorov

Appl. Phys. Lett. 90, 261905 (2007); http://dx.doi.org/10.1063/1.2751597 (3 pages) | Cited 6 times

Online Publication Date: 25 June 2007

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The authors report on fabrication and hydrogen separation performance of an array of thin, freestanding Pd/Ag alloy membranes. Film deposition from an alloyed sputtering target results in robust film characteristics. Long-term stability of the membranes has been demonstrated with experimental testing at temperatures of 473–627 K. Within the testing period the membrane has withstood more than 30 thermal cycles by returning to ambient temperature between subsequent tests. Throughout the long-term testing, hydrogen permeation levels have increased by more than a factor of 2. Electron microscopy of the membranes indicates that performance enhancement is due to microstructural changes which are promoted at elevated temperatures.
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81.05.Bx Metals, semimetals, and alloys
82.45.Mp Thin layers, films, monolayers, membranes
81.15.Cd Deposition by sputtering

Pd–In–Fe shape memory alloy

H. Ishikawa, Y. Sutou, T. Omori, K. Oikawa, K. Ishida, A. Yoshikawa, R. Y. Umetsu, and R. Kainuma

Appl. Phys. Lett. 90, 261906 (2007); http://dx.doi.org/10.1063/1.2749440 (3 pages) | Cited 3 times

Online Publication Date: 26 June 2007

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Martensitic, magnetic transformations, and crystal structures in Pd–In–Fe alloys were investigated. It was confirmed that some Pd–In–Fe alloys show martensitic transformation from a Heusler-type (L21) ordered bcc phase to a 2M-type (DO22) structure and that an almost perfect superelastic effect accompany the transformation can be obtained. Furthermore, some alloys show transformation from the paramagnetic parent phase to the ferromagnetic martensite phase.
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81.30.Kf Martensitic transformations
64.70.K- Solid-solid transitions
75.30.Kz Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.)
61.66.Dk Alloys
81.40.Jj Elasticity and anelasticity, stress-strain relations
75.50.Bb Fe and its alloys

Mechanism for radiative recombination in ZnCdO alloys

I. A. Buyanova, J. P. Bergman, G. Pozina, W. M. Chen, S. Rawal, D. P. Norton, S. J. Pearton, A. Osinsky, and J. W. Dong

Appl. Phys. Lett. 90, 261907 (2007); http://dx.doi.org/10.1063/1.2751589 (3 pages) | Cited 12 times

Online Publication Date: 26 June 2007

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Temperature dependent cw- and time-resolved photoluminescence combined with absorption measurements are employed to evaluate the origin of radiative recombination in ZnCdO alloys grown by molecular-beam epitaxy. The near-band-edge emission is attributed to recombination of excitons localized within band tail states likely caused by nonuniformity in Cd distribution. Energy transfer between the tail states is argued to occur via tunneling of localized excitons. The transfer is shown to be facilitated by increasing Cd content due to a reduction of the exciton binding energy and, therefore, an increase of the exciton Bohr radius in the alloys with a high Cd content.
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81.05.Dz II-VI semiconductors
73.61.Ga II-VI semiconductors
73.50.Gr Charge carriers: generation, recombination, lifetime, trapping, mean free paths
81.15.Hi Molecular, atomic, ion, and chemical beam epitaxy
78.55.Et II-VI semiconductors
71.35.-y Excitons and related phenomena

Facile assembling of gold nanorods with large aspect ratio and their surface-enhanced Raman scattering properties

Go Kawamura, Yong Yang, and Masayuki Nogami

Appl. Phys. Lett. 90, 261908 (2007); http://dx.doi.org/10.1063/1.2752026 (3 pages) | Cited 21 times

Online Publication Date: 26 June 2007

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Linear- and parallel-aligned gold nanorods (GNRs) were self-assembled on glass substrates and their surface-enhanced Raman scattering effect was investigated. GNRs were prepared by seed-mediated growth method and self-assembled to form linear and parallel aggregation on the substrate. The parallel-aligned GNRs showed weak optical absorption intensities in the visible to infrared wavelength region. On the other hand, the linear-aligned GNRs exhibited strong optical absorption bands peaking at 830 and 2200 nm, which are assigned to the weakly coupled surface plasmons of the GNRs. When Rhodamine-6G molecules were adsorbed on the linear-aligned GNRs, strong surface-enhanced Raman scattering spectra were observed.
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78.30.Er Solid metals and alloys
61.46.Df Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)
81.16.Dn Self-assembly
78.67.Bf Nanocrystals, nanoparticles, and nanoclusters
68.43.Mn Adsorption kinetics
78.40.Kc Metals, semimetals, and alloys
73.20.Mf Collective excitations (including excitons, polarons, plasmons and other charge-density excitations)

Epitaxial electrodeposition of freestanding large area single crystal substrates

Jae Wook Shin, Adam Standley, and Eric Chason

Appl. Phys. Lett. 90, 261909 (2007); http://dx.doi.org/10.1063/1.2752531 (3 pages)

Online Publication Date: 26 June 2007

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The authors report on a method for producing freestanding single crystal metal films over large areas using electrodeposition and selective etching. The method can be turned into an inexpensive continuous process for making long ribbons or a large area of single crystal films. Results from a 5×5 mm2 Ni single crystal film using electron backscattering pattern pole figures and x-ray diffraction demonstrate that the quality of material produced is equivalent to the initial substrate without annealing or polishing.
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81.15.Pq Electrodeposition, electroplating
68.55.A- Nucleation and growth
81.05.Bx Metals, semimetals, and alloys
82.45.Qr Electrodeposition and electrodissolution
81.65.Cf Surface cleaning, etching, patterning
68.55.-a Thin film structure and morphology

Stabilization of the liquid crystal director in the patterned vertical alignment mode through formation of pretilt angle by reactive mesogen

Sang Gyun Kim, Sung Min Kim, Youn Sik Kim, Hee Kyu Lee, Seung Hee Lee, Gi-Dong Lee, Jae-Jin Lyu, and Kyeong Hyeon Kim

Appl. Phys. Lett. 90, 261910 (2007); http://dx.doi.org/10.1063/1.2752105 (3 pages) | Cited 40 times

Online Publication Date: 27 June 2007

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In the patterned vertical alignment (PVA) cell in which multidomains are formed from the perfect vertical alignment through an oblique field only, the formation of disclinations between liquid crystal (LC) molecules is inevitable in the presence of an electric field, which lowers transmittance and the response time. In the proposed PVA device, the pretilt angle is formed in four different directions through the polymerization of an UV curable reactive mesogen monomer at the surface. In this way, the reorientation of LC responding to an electric field is well defined, and thus the device shows reduced threshold voltage and much improved response time in all gray scales.
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42.79.Kr Display devices, liquid-crystal devices

Radiation and polarization properties of free-exciton emission from AlN (0001) surface

Yoshitaka Taniyasu, Makoto Kasu, and Toshiki Makimoto

Appl. Phys. Lett. 90, 261911 (2007); http://dx.doi.org/10.1063/1.2752727 (3 pages) | Cited 25 times

Online Publication Date: 27 June 2007

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Free-exciton emission from AlN (0001) surface was characterized by angle-dependent photoluminescence (PL) measurement. As the radiation direction was inclined from the surface normal (c-axis direction), the emission intensity increased. This is because the optical transition between the conduction band and the top valence band is mainly allowed for light with the electric field parallel to the c-axis direction of AlN (Ec) and consequently the free-exciton emission is strongly polarized for Ec. By analyzing the angle-dependent PL intensities, the polarization ratio was estimated to be 0.995. This high polarization ratio results from the large negative crystal-field splitting energy.
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73.20.At Surface states, band structure, electron density of states
71.35.-y Excitons and related phenomena
78.55.Cr III-V semiconductors
71.70.Ch Crystal and ligand fields

Efficient green emission from (11math2) InGaN/GaN quantum wells on GaN microfacets probed by scanning near field optical microscopy

Y. Kawakami, K. Nishizuka, D. Yamada, A. Kaneta, M. Funato, Y. Narukawa, and T. Mukai

Appl. Phys. Lett. 90, 261912 (2007); http://dx.doi.org/10.1063/1.2748309 (3 pages) | Cited 9 times

Online Publication Date: 28 June 2007

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Nanoscopic optical characterization using scanning near field optical microscopy was performed on a (11math2) microfacet quantum well (QW). It was revealed that the carrier diffusion length in the (11math2) QW is less than the probing fiber aperture of 160 nm, which is shorter than that of the (0001) QWs and is attributed to much faster radiative recombination processes in the (11math2) QW due to a reduced internal electric field. Owing to this short diffusion length, the correlation between the internal quantum efficiency (IQE) and emission wavelength is elucidated. The highest IQE is ∼ 50% at 520 nm, which is about 50 nm longer than in (0001) QWs, suggesting that the (11math2) QW is a suitable green emitter.
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78.67.De Quantum wells
78.55.Cr III-V semiconductors

Photoluminescent behavior of SrBi2Nb2O9 powders explained by means of β-Bi2O3 phase

D. P. Volanti, L. S. Cavalcante, E. C. Paris, A. Z. Simões, D. Keyson, V. M. Longo, A. T. de Figueiredo, E. Longo, J. A. Varela, F. S. De Vicente, and A. C. Hernandes

Appl. Phys. Lett. 90, 261913 (2007); http://dx.doi.org/10.1063/1.2753114 (3 pages) | Cited 16 times

Online Publication Date: 28 June 2007

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Photoluminescence (PL) behavior of SrBi2Nb2O9 (SBN) powders was explained by means of β-Bi2O3 phase on the SBN lattice. Oxygen vacancies and recombination of electrons holes in the valence band lead to the formation of [NbO5VOx], [NbO5VO] and [NbO5VO••] complex clusters which are the main reason for the PL at room temperature. X-ray diffraction and Fourier transform Raman spectroscopy were used as tools to investigate the structural changes in SBN lattice allowing to correlate [NbO5VO]/[NbO6]′ ratio with the evolution of the visible PL emission in the SBN powders.
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78.55.Hx Other solid inorganic materials
61.43.Gt Powders, porous materials
61.72.J- Point defects and defect clusters
72.20.Jv Charge carriers: generation, recombination, lifetime, and trapping
78.30.Hv Other nonmetallic inorganics

Optical emission of directly contacted copper/sapphire interface under shock compression of megabar

G. Y. Hao, F. S. Liu, D. Y. Zhang, and M. J. Zhang

Appl. Phys. Lett. 90, 261914 (2007); http://dx.doi.org/10.1063/1.2751606 (3 pages) | Cited 2 times

Online Publication Date: 29 June 2007

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The shock-induced optical emission histories from copper/sapphire interface were measured under two different contact conditions, which simulated the typical situations of pyrometry experiments. Results showed that the “peak” feature of the radiation, previously interpreted as the appearance of so-called high-temperature layer, was nearly diminished by finely polishing and uniformly prepressing technique, and that it is possible to directly measure the equilibrium temperature of bulk metal/window interface. Study also demonstrated that the saturated value of the apparent temperature in nonideal contact situation is related to the color temperature of the shock-induced “bright spot” in sapphire window under megabar pressures.
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62.50.-p High-pressure effects in solids and liquids
62.20.F- Deformation and plasticity
81.40.Lm Deformation, plasticity, and creep
78.60.Mq Sonoluminescence, triboluminescence
81.65.Ps Polishing, grinding, surface finishing
78.20.hb Piezo-optical, elasto-optical, acousto-optical, and photoelastic effects

Implant damage and strain relaxation of embedded epitaxial silicon germanium layer on silicon

J. P. Liu, J. Li, A. See, M. S. Zhou, and L. C. Hsia

Appl. Phys. Lett. 90, 261915 (2007); http://dx.doi.org/10.1063/1.2749868 (3 pages) | Cited 5 times

Online Publication Date: 29 June 2007

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The authors report on the implant damage and strain relaxation in embedded silicon germanium (SiGe) layer, selectively grown on recessed silicon (Si) (001) with different recess length (defined as [110] direction, along the conventional Si transistor channel) and the same width (defined as [1−10] direction). Similar to the implant damage in blanket epi-SiGe layers on Si (001) reported previously, they observed two defect bands, one close to the surface and the other at SiGe/Si interface. Unlike the biaxial strain relaxation with misfit dislocations equally distributed along both the [110] and [1−10] directions in blanket epi-SiGe layers on Si (001), there is a gradual change from biaxial to uniaxial relaxation with misfit dislocations along only at the [1−10] direction and a decreasing density of misfit dislocation, with decreasing recess length.
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81.40.Lm Deformation, plasticity, and creep
62.20.F- Deformation and plasticity
61.72.Ff Direct observation of dislocations and other defects (etch pits, decoration, electron microscopy, x-ray topography, etc.)

Low-frequency eigenvibrations of hollow carbon microspheres

Y. Li, H. S. Lim, S. C. Ng, M. H. Kuok, F. Su, and X. S. Zhao

Appl. Phys. Lett. 90, 261916 (2007); http://dx.doi.org/10.1063/1.2753117 (3 pages) | Cited 1 time

Online Publication Date: 29 June 2007

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Monodisperse hollow carbon microspheres have been fabricated using silica spheres as templates via a three-step chemical vapor deposition method. The vibrational eigenmodes of these hollow carbon microspheres have been measured by Brillouin light scattering. The frequencies of the eigenvibrations of a free surface hollow carbon sphere are also calculated within the framework of the elasticity theory. A comparison of the theoretical and measured frequencies shows that the observed Brillouin peaks are due to the spheroidal modes of the hollow spheres.
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63.22.-m Phonons or vibrational states in low-dimensional structures and nanoscale materials
78.35.+c Brillouin and Rayleigh scattering; other light scattering

Use of real-time Fourier transform infrared reflectivity as an in situ monitor of YBa2Cu3O7 film deposition and processing

Gertjan Koster, Jeong-Uk Huh, R. H. Hammond, and M. R. Beasley

Appl. Phys. Lett. 90, 261917 (2007); http://dx.doi.org/10.1063/1.2753118 (3 pages) | Cited 2 times

Online Publication Date: 29 June 2007

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Fourier transform infrared reflectivity (FTIR) has been utilized as an in situ, real-time diagnostic during high-rate, e-beam deposition of YBa2Cu3O7 (YBCO). The results demonstrate the great utility of FTIR as an in situ monitor of YBCO deposition and postdeposition processing. They also point to a completely different picture of the nature and associated kinetic and thermodynamic pathways of the high-rate, e-beam process, both during deposition and as a function of subsequent trajectories through temperature and oxygen pressure space.
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74.78.-w Superconducting films and low-dimensional structures
81.15.-z Methods of deposition of films and coatings; film growth and epitaxy
74.25.Gz Optical properties
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Anharmonic behavior in microwave-driven resistivity oscillations in Hall bars

Jesús Iñarrea

Appl. Phys. Lett. 90, 262101 (2007); http://dx.doi.org/10.1063/1.2751585 (3 pages) | Cited 13 times

Online Publication Date: 25 June 2007

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The authors analyzed the magnetoresistivity of a two-dimensional electron system excited by microwave radiation in a regime of high intensities and low frequencies. In such a regime, recent experiments show that different features appear in the magnetoresistivity response which suggest an anharmonic behavior. These features consist mainly of distorted oscillations and new resonance peaks at the subharmonics of the cyclotron frequency. They follow the model of microwave-driven electron orbit motions which become anharmonic when the ratio of microwave intensity to microwave frequency is large enough.
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72.30.+q High-frequency effects; plasma effects
73.63.-b Electronic transport in nanoscale materials and structures

Microphotoreflectance spectroscopy of heterojunction bipolar transistors under biasing voltage: Measurement of the net doping concentration

Houssam Chouaib and Catherine Bru-Chevallier

Appl. Phys. Lett. 90, 262102 (2007); http://dx.doi.org/10.1063/1.2751591 (3 pages) | Cited 3 times

Online Publication Date: 25 June 2007

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The authors present a microphotoreflectance (micro-PR) spectroscopic study of a biased InGaAlAs/GaAsSb/InP heterojunction bipolar transistor. Franz Keldysh oscillations from an InGaAlAs emitter are studied as a function of the static biasing voltage applied to the emitter-base junction. The electric field value from the InGaAlAs emitter is decreasing under direct biasing voltage. The change in electric field value is shown to be in good agreement within the expected operation of forward biased junction, and making possible a straight measurement of the net doping concentration. Results show the feasibility of a micro-PR spectroscopy analysis of devices under operation.
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85.30.Pq Bipolar transistors

Molecular-based light-activated thyristor

Toshifumi Iimori, Nobuhiro Ohta, and Toshio Naito

Appl. Phys. Lett. 90, 262103 (2007); http://dx.doi.org/10.1063/1.2749845 (3 pages) | Cited 10 times

Online Publication Date: 25 June 2007

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A photoinduced electrical conductivity switching is observed in the molecular conductor of α-[bis(ethylenedithio)tetrathiafulvalene]2I3 at different temperatures with different irradiation light intensities. The threshold voltage for the differential-negative-resistance effect appearing in the current-voltage characteristic curve decreases and increases, respectively, as the light intensity is increased and as the temperature decreases below the insulator-metal phase transition. The potential application of molecular conductor in bidirectional light-activated thyristor devices is demonstrated.
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85.65.+h Molecular electronic devices
85.60.-q Optoelectronic devices

Ambipolar field-effect transistor based on organic-inorganic hybrid structure

Hajime Nakanotani, Masayuki Yahiro, Chihaya Adachi, and Koki Yano

Appl. Phys. Lett. 90, 262104 (2007); http://dx.doi.org/10.1063/1.2752023 (3 pages) | Cited 13 times

Online Publication Date: 26 June 2007

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The authors developed an ambipolar field-effect transistor (FET) based on an organic-inorganic hybrid structure that consisted of an indium zinc oxide and pentacene double layer fabricated on a SiO2/n++-Si substrate. Although the FETs based on an indium zinc oxide or pentacene single layer only showed unipolar FET characteristics, the hybrid FET showed definite ambipolar FET characteristics. The authors obtained a highly saturated field-effect hole and electron mobilities of 0.14 and 13.8 cm2/Vs. Furthermore, the authors demonstrated electroluminescence from hybrid FETs using tetracene as an emitting layer. The authors’ success shows that the hybridization of organic and inorganic materials opens up a new field in electronics.
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85.30.Tv Field effect devices
85.30.De Semiconductor-device characterization, design, and modeling

14 MHz organic diodes fabricated using photolithographic processes

Yuming Ai, Srinivas Gowrisanker, Huiping Jia, Isaac Trachtenberg, Eric Vogel, Robert M. Wallace, Bruce E. Gnade, Raymond Barnett, Harvey Stiegler, and Hal Edwards

Appl. Phys. Lett. 90, 262105 (2007); http://dx.doi.org/10.1063/1.2752533 (3 pages) | Cited 15 times

Online Publication Date: 26 June 2007

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Organic semiconductor-based Schottky diodes operating at 14 MHz, fabricated using conventional photolithographic and etching processes, have been demonstrated. Copper phthalocyanine is the semiconductor, with gold and aluminum as the Ohmic and Schottky contacts, respectively. The organic diode based rectifier circuit generated a dc output voltage of approximately 2 V at 14 MHz, using an input ac signal with a zero-to-peak voltage amplitude of 5 V. These devices showed little degradation under continuous ac voltage stress when operated in vacuum.
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85.30.Kk Junction diodes
85.40.Hp Lithography, masks and pattern transfer

Improvements in the device characteristics of amorphous indium gallium zinc oxide thin-film transistors by Ar plasma treatment

Jin-Seong Park, Jae Kyeong Jeong, Yeon-Gon Mo, Hye Dong Kim, and Sun-Il Kim

Appl. Phys. Lett. 90, 262106 (2007); http://dx.doi.org/10.1063/1.2753107 (3 pages) | Cited 99 times

Online Publication Date: 26 June 2007

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The effect of Ar plasma treatment on amorphous indium gallium zinc oxide (a-IGZO) thin films was investigated. The net electron carrier concentration (1020–1021 cm−3) of the a-IGZO thin films dramatically increased upon their exposure to the Ar plasma compared to that (1014 cm−3) of the as-deposited thin film. The authors attempted to reduce the contact resistance between the Pt/Ti (source/drain electrode) and a-IGZO (channel) by using the Ar plasma treatment. Without the treatment, the a-IGZO thin film transistors (TFTs) with W/L = 50/4 μm exhibited a moderate field-effect mobility (μFE) of 3.3 cm2/Vs, subthreshold gate swing (S) of 0.25 V/decade, and Ion/off ratio of 4×107. The device performance of the a-IGZO TFTs was significantly improved by the Ar plasma treatment. As a result, an excellent S value of 0.19 V/decade and high Ion/off ratio of 1×108, as well as a high μFE of 9.1 cm2/Vs, were achieved for the treated a-IGZO TFTs.
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85.30.Tv Field effect devices
73.40.Cg Contact resistance, contact potential
72.20.Fr Low-field transport and mobility; piezoresistance
73.61.Jc Amorphous semiconductors; glasses

Polymer functionalized piezoelectric-FET as humidity/chemical nanosensors

Chang Shi Lao, Qin Kuang, Zhong L. Wang, Myung-Chul Park, and Yulin Deng

Appl. Phys. Lett. 90, 262107 (2007); http://dx.doi.org/10.1063/1.2748097 (3 pages) | Cited 32 times

Online Publication Date: 27 June 2007

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By coating one side of the surface of a ZnO nanobelt (NB) with multilayer polymers using an electrostatic self-assembling process, a humidity/chemical nanosensor based on piezoelectric field effect transistor (PE-FET) is demonstrated. The working principle of the PE-FET relies on the self-contraction/expansion of the polymer, which builds up a strain in the piezoelectric NB and induces a potential drop across the NB that serves as the gate voltage for controlling the current flowing through the NB. The response of PE-FET to the phase transition of the coating polymer was also demonstrated. The device is a component for nanopiezotronics.
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07.07.Df Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing
85.30.Tv Field effect devices
85.50.-n Dielectric, ferroelectric, and piezoelectric devices
85.35.-p Nanoelectronic devices

Graphitization of polymer surfaces by low-energy ion irradiation

I. Lazareva, Y. Koval, M. Alam, S. Strömsdörfer, and P. Müller

Appl. Phys. Lett. 90, 262108 (2007); http://dx.doi.org/10.1063/1.2752738 (3 pages) | Cited 6 times

Online Publication Date: 27 June 2007

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The surface of several polymers was graphitized by low-energy ion irradiation. Their conducting properties were studied as a function of the energy of the ions and the irradiation temperature. It was found that at rather modest ion energies ( ∼ 1000 eV) and irradiation temperatures (<400 °C), polymer surfaces transform to a graphitized state. The graphitized layer consists of overlapping graphite islands with a diameter of 1–3 nm and exhibits a semimetallic conductivity. Gradually reducing the energy of the ions and the irradiation temperature, the authors observed a transition from semimetallic to variable range hopping conductivity.
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68.47.Mn Polymer surfaces
68.35.Rh Phase transitions and critical phenomena
72.20.Ee Mobility edges; hopping transport
72.60.+g Mixed conductivity and conductivity transitions
61.82.Pv Polymers, organic compounds
61.80.Jh Ion radiation effects

Defect generation at the SiSiO2 interface following corona charging

Hao Jin, K. J. Weber, N. C. Dang, and W. E. Jellett

Appl. Phys. Lett. 90, 262109 (2007); http://dx.doi.org/10.1063/1.2749867 (3 pages) | Cited 7 times

Online Publication Date: 28 June 2007

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A combination of capacitance-voltage and lifetime decay measurements is used to show that corona biasing of silicon oxidized samples results in the generation of additional interface defects and an increase in surface recombination. The onset of interface degradation occurs at relatively low electric fields, estimated to be less than ∼ +/−1.2 MV/cm. The majority of the defects generated by corona biasing can be removed by a short annealing at 400 °C. The results are consistent with the hypothesis that atomic hydrogen is chiefly responsible for the observed degradation. Corona biasing, even at low electric fields, cannot be relied on as a noninvasive characterization tool.
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77.84.Bw Elements, oxides, nitrides, borides, carbides, chalcogenides, etc.
73.20.Hb Impurity and defect levels; energy states of adsorbed species
73.40.Qv Metal-insulator-semiconductor structures (including semiconductor-to-insulator)
73.50.Gr Charge carriers: generation, recombination, lifetime, trapping, mean free paths
73.25.+i Surface conductivity and carrier phenomena
81.65.Rv Passivation

Evidence of electron accumulation at nonpolar surfaces of InN nanocolumns

E. Calleja, J. Grandal, M. A. Sánchez-García, M. Niebelschütz, V. Cimalla, and O. Ambacher

Appl. Phys. Lett. 90, 262110 (2007); http://dx.doi.org/10.1063/1.2749871 (3 pages) | Cited 37 times

Online Publication Date: 28 June 2007

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High-quality InN nanocolumns grown by molecular beam epitaxy on n-type Si(111) have been electrically characterized by atomic force microscopy. Current-voltage characteristics were measured on InN nanocolumns with similar heights but different diameters. The conductivity scales the nanocolumns reciprocal diameter, pointing to the nanocolumn lateral surface as the main conduction path. These results, opposing those found in undoped GaN nanocolumns where the conductivity is rather independent of the diameter (conduction through the volume), agree well with a model that predicts electron accumulation by Fermi level pinning within the conduction band on nonpolar (m plane) InN surfaces reconstructed under In-rich conditions.
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73.63.Bd Nanocrystalline materials
73.22.-f Electronic structure of nanoscale materials and related systems
73.20.At Surface states, band structure, electron density of states

Direct observation of relaxation dynamics of spin-polarized electrons excited at a higher-energy spin-split subband in a diluted magnetic semiconductor quantum well

K. Saito, J. H. Park, I. Souma, Y. Oka, and A. Murayama

Appl. Phys. Lett. 90, 262111 (2007); http://dx.doi.org/10.1063/1.2753091 (3 pages) | Cited 2 times

Online Publication Date: 28 June 2007

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The authors observe relaxation dynamics of spin-polarized electrons excited at a higher-energy spin-split subband in a diluted magnetic semiconductor quantum well by means of pump-probe absorption spectroscopy. Time dependences of the circularly polarized saturated absorbance directly show the relaxation of spin-polarized electrons, which is inaccessible by photoluminescence. The probe-energy dependence of the relaxation time is obtained ranging from 2 to 100 ps at 2.5 T within the absorption band. This dependence is systematically explained by both the intraband energy relaxation of the spin-polarized electrons and the subsequent electron-spin relaxation that is modified by effects of the exciton localization.
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73.63.Hs Quantum wells
78.67.De Quantum wells
72.25.Dc Spin polarized transport in semiconductors
75.50.Pp Magnetic semiconductors
78.55.Et II-VI semiconductors
71.35.-y Excitons and related phenomena
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