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Appl. Phys. Lett. 90, 083117 (2007); http://dx.doi.org/10.1063/1.2696653 (3 pages)

Nanoscale switch elements from self-assembled monolayers on silver

Jeremy M. Beebe and James G. Kushmerick

National Institute of Standards and Technology, Gaithersburg, Maryland 20899

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(Received 20 November 2006; accepted 20 January 2007; published online 23 February 2007)

Au/molecule/Ag junctions are shown to behave as voltage-controlled two-state switches. In the open state, the current-voltage behavior is consistent with a metal-molecule-metal tunnel junction. At a negative bias threshold, silver filaments bridge the gap between the two electrodes, resulting in direct metal-metal contact and an increase in current of several orders of magnitude. Under positive bias, the filaments dissolve, returning the switch to an open state. Switching rates of up to ≈ 10 kHz have been observed. Because the only required components are silver and a self-assembled monolayer, this switch element can be incorporated into a wide array of device architectures.

© 2007 American Institute of Physics

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0003-6951 (print)  
1077-3118 (online)

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