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Appl. Phys. Lett. 96, 263504 (2010); http://dx.doi.org/10.1063/1.3458596 (3 pages)

Electrical nanocharacterization of copper tetracyanoquinodimethane layers dedicated to resistive random access memories

Damien Deleruyelle1, Christophe Muller1, Julien Amouroux1, and Robert Müller2

1IM2NP, Aix-Marseille Université, UMR CNRS 6242, 38 rue Joliot Curie, 13451 Marseille Cedex 20, France
2Interuniversity MicroElectronics Center v.z.w. (IMEC), Kapeldreef 75, B-3001 Leuven, Belgium

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(Received 23 April 2010; accepted 7 June 2010; published online 28 June 2010)

The local electrical properties of copper tetracyanoquinodimethane (CuTCNQ)/HfO2/Pt stacks were investigated thanks to conductive-atomic force microscopy (AFM) measurements. Local I-V and I-t spectroscopy evidenced repeatable and reversible bipolar electrical switching (SET and RESET operations) at the nanometer scale beneath the AFM tip. Experimental results suggest that resistive switching is due to the creation/dissolution of conductive filaments bridging the CuTCNQ surface to the AFM tip. A physical model based on the migration of Cu+ ions within a nanogap and the growth of a conductive filament shows an excellent agreement with the experimental results during SET operation achieved at nanoscale.

© 2010 American Institute of Physics

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KEYWORDS and PACS

PACS

  • 84.30.Sk

    Pulse and digital circuits

  • 73.63.-b

    Electronic transport in nanoscale materials and structures

ARTICLE DATA

PUBLICATION DATA

ISSN

0003-6951 (print)  
1077-3118 (online)

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