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Appl. Phys. Lett. 96, 263506 (2010); http://dx.doi.org/10.1063/1.3456530 (3 pages)

Effects of cathode buffer layers on the efficiency of bulk-heterojunction solar cells

Ching-Chun Chang1, Chi-Feng Lin2, Jian-Ming Chiou3, Tzung-Han Ho4, Yian Tai3, Jiun-Haw Lee2, Yang-Fang Chen4, Juen-Kai Wang5, Li-Chyong Chen5, and Kuei-Hsien Chen1,5

1Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan
2Graduate Institute of Photonics and Optoelectronics, National Taiwan University, Taipei 106, Taiwan
3Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 106, Taiwan
4Department of Physics, National Taiwan University, Taipei 106, Taiwan
5Center for Condensed Matter Science, National Taiwan University, Taipei 106, Taiwan

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(Received 28 March 2010; accepted 19 May 2010; published online 28 June 2010; corrected 8 July 2010)

The effects of cathode buffer layers on the bulk-heterojunction solar cells are investigated. Comparing with the device without buffer layer, obvious enhancements of Voc from 0.38 to 0.65 V and fill factor from 44% to 63% have been achieved by using 2 nm bathocuproine layer, which make the efficiency of the devices improved from 1.63% to 4.11%. Alternatively, lithium fluoride and/or tris(8-hydroxyquinolinato) aluminum were also introduced for clarification purpose. X-ray photoelectron spectroscopy study indicates that the degradation caused by the outer diffusion of carbon from active layers plays a crucial role in the device performance.

© 2010 American Institute of Physics

EDITORIALLY RELATED

  1. Publisher's Note: “Effects of cathode buffer layers on the efficiency of bulk-heterojunction solar cells” [Appl. Phys. Lett. 96, 263506 (2010)]
    Ching-Chun Chang et al.
    Appl. Phys. Lett. 97, 049901 (2010)APPLAB000097000004049901000001

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0003-6951 (print)  
1077-3118 (online)

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