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Appl. Phys. Lett. 99, 193307 (2011); http://dx.doi.org/10.1063/1.3660708 (3 pages)

Near-infrared absorbing semitransparent organic solar cells

Jan Meiss, Felix Holzmueller, Roland Gresser, Karl Leo, and Moritz Riede

Institut für Angewandte Photophysik, Technische Universität Dresden, 01062 Dresden, Germany

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(Received 8 September 2011; accepted 26 October 2011; published online 11 November 2011)

We present efficient, semitransparent small molecule organic solar cells. The devices employ an indium tin oxide-free top contact, consisting of thin metal films and an additional organic capping layer for enhanced light in/outcoupling. The solar cell encorporates a bulk heterojunction with the donor material Ph2-benz-bodipy, an infrared absorber. Combination of Ph2-benz-bodipy with C60 as acceptor leads to devices with high open circuit voltages of up to 0.81 V and short circuit current densities of 5-6 mA/cm2, resulting in efficiences of 2.2%-2.5%. At the same time, the devices are highly transparent, with an average transmittance in the visible range (400-750 nm) of up to 47.9%, with peaks at 538 nm of up to 64.2% and an average transmittance in the yellow-green range of up to 61.8%.

© 2011 American Institute of Physics

KEYWORDS and PACS

PACS

  • 88.40.jr

    Organic photovoltaics

  • 88.40.hj

    Efficiency and performance of solar cells

  • 78.20.Ci

    Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity)

ARTICLE DATA

PUBLICATION DATA

ISSN

0003-6951 (print)  
1077-3118 (online)

  1. M. A. Green, K. Emery, Y. Hishikawa, and W. Warta, Prog. Photovoltaics 19, 84 (2011).
  2. A. Henemann, Renewable Energy Focus 9(1), 14 (2008).
  3. J. Meiss, M. K. Riede, and K. Leo, J. Appl. Phys. 105, 063108 (2009)JAPIAU000105000006063108000001.
  4. B. O'Connor, K. H. An, K. P. Pipe, Y. Zhao, and M. Shtein, Appl. Phys. Lett. 89, 233502 (2006).
  5. J. Meiss, N. Allinger, M. K. Riede, and K. Leo, Appl. Phys. Lett. 93, 103311 (2009)APPLAB000093000010103311000001.
  6. J. Meiss, T. Menke, C. Uhrich, W.-M. Gnehr, S. Sonntag, M. Pfeiffer, K. Leo, and M. K. Riede, Appl. Phys. Lett. 99, 043301 (2011)APPLAB000099000004043301000001.
  7. R. R. Lunt and V. Bulovic, Appl. Phys. Lett. 98(11), 113305 (2011)APPLAB000098000011113305000001.
  8. R. Gresser, M. Hummert, H. Hartmann, K. Leo, and M. Riede, Chem. Eur. J. 17, 2939 (2011).
  9. F. Li, M. Pfeiffer, A. G. Werner, K. Harada, K. Leo, N. Hayashi, K. Seki, X. Liu, and X.-D. Dang, J. Appl. Phys. 100, 023716 (2006)JAPIAU000100000002023716000001.
  10. J. Meyer, S. Hamwi, S. Schmale, T. Winkler, H.-H. Johannes, T. Riedl, and W. Kowalsky, J. Mater. Chem. 19, 702 (2009).
  11. E. Centurioni, Appl. Opt. 44(35), 7532 (2005). [MEDLINE]
  12. developed by Mauro Furno at IAPP.

Figures (4) Tables (1)

Figures (click on thumbnails to view enlargements)

FIG.1
(Color online) (a) Structure of the absorber material Ph2-benz-bodipy; (b) schematic of the solar cell stack; (c) picture of the lighthouse of Hörnum, photographed with a SMOSC substrate on top. The active area is marked with the black arrow.

FIG.1 Download High Resolution Image (.zip file) | Export Figure to PowerPoint

FIG.2
(Color online) Top: j(V) curves of the SMOSC, illuminated either through the top contact (low current densities) or through the substrate (high current densities). Bottom: EQE, measured through the substrate.

FIG.2 Download High Resolution Image (.zip file) | Export Figure to PowerPoint

FIG.3
(Color online) Transmittance and reflectance of the active areas, measured for bottom illumination.

FIG.3 Download High Resolution Image (.zip file) | Export Figure to PowerPoint

FIG.4
(Color online) Absorbed photon flux of metal top contact and photoactive layers under simulated AM 1.5 G illumination through the substrate (filled symbols) or through the metal top contact (empty symbols) at 14 nm Ag and 75 nm Al33.

FIG.4 Download High Resolution Image (.zip file) | Export Figure to PowerPoint

Tables

Table I. Summary of the current-voltage parameters. Top three rows: top illumination and bottom five rows: bottom ilumination. The values of tAg and tAlq3 represent the metal and capping layer thickness, respectively. The average visible transmission TVIS is calculated in the range from 400-750 nm, the yellow-green TYG from 495-590 nm.

View Table


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